Issue 
EPJ Appl. Metamat.
Volume 5, 2018
Metamaterials'2017 – Metamaterials and Novel Wave Phenomena: Theory, Design and Application



Article Number  4  
Number of page(s)  7  
DOI  https://doi.org/10.1051/epjam/2017013  
Published online  06 March 2018 
https://doi.org/10.1051/epjam/2017013
Research Article
Broadband absorption with gradient metasurfaces
Department of Electrical and Computer Engineering, The University of Texas at Austin,
Austin,
TX
78712, USA
^{*} email: alu@mail.utexas.edu
Received:
29
September
2017
Accepted:
28
November
2017
Published online: 6 March 2018
A metasurface with appropriately designed transverse spatial inhomogeneities can provide the desired phase redistribution in response to an incident wave with arbitrary incident angle. This property of gradient metasurfaces has been used to modify light propagation in unusual manners, to transform the impinging optical wavefront with large flexibility. In this work, we show how gradient metasurfaces can be tailored to offer high absorption in thin absorptive layers, and how to design realistic metasurfaces for this purpose using dielectric materials.
© H. Kwon et al., published by EDP Sciences, 2018
This is an Open Access article distributed under the terms of the Creative Commons Attribution License (http://creativecommons.org/licenses/by/4.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
1 Introduction
Metamaterials have attracted significant attention in recent years, for a wide range of applications, including invisibility, guiding phase or energy of electromagnetic waves in unusual manners, and several others [1–18]. The investigation of metasurfaces can be connected with a large body of work in the radio frequency spectrum studying the design and realization of frequencyselective surfaces and other thin resonant artificial screens for several decades [19–25]. With the development of nanotechnology and the possibility of fabricating nanoscale structures, similar methods have expanded towards the visible range of the electromagnetic spectrum [26–37]. Recent studies on metasurfaces have shown that it is possible to generalize the conventional Snell's law at the interface between two media, as well as controlling the power flow into different diffraction channels using periodic metagratings [38–40]. Metasurfaces are able to support these unusual reflection and refraction properties by leveraging spatial inhomogeneities over a surface that introduces phase variation on impinging wavefront, and reflect and refract in abnormal ways. In this paper, we envision that this approach, phasegradient metasurfaces, can be realized under an absorptive layer, and tailored to introduce longer traveling paths to enhance energy harvesting and offer large absorption efficiency. Increasing the efficiency of solar energy harvesting can be particularly relevant, given the essentially unlimited amount of available energy. Using metasurfaces for solar energy harvesting applications can provide large efficiency enhancements, of direct importance for the growing field of nanophotonic management of solar panels.
Efficient light deflection and steering can be achieved by locally controlling the surface admittance and impedance over the surface [27,28]. The local reflection coefficient Γ(x) and transmission T(x) can be tailored to control locally the phase front, and imprinting on it a desired pattern [41,42]. The admittance distribution of ideal metasurfaces controls the phase of incident light over the complete 2π phase range across the surface. Here, we assume normally incident light from the farfieldlight incidence from the farfield at normal incid, but, as shown in [34], the operation of gradient metasurfaces is inherently broadband and broad angle, so the response is expected to be robust to other incidence angles around normal direction, consistent with the major portion of impinging energy from the sun. Figure 1a shows how an ideal admittance profile can change the response of the surface under normal incident light. When normally incident light is deflected with metasurfaces towards an angle θ_{r}, three main deflection modes are supported for deflection angles over θ_{r} > 30^{∘}, and the other Floquet modes are evanescent. By locally tuning the surface impedance and admittance, we can make one diffraction order to be dominant compared to the other two, or we can scatter the incident light symmetrically into higherorder diffraction orders to be trapped inside the substrate.
Here, after studying the optimal impedance distributions to trap light into a small absorbing layer, we explore the realistic implementation of these metasurfaces using realistic nanostructured materials. We consider several requirements on the involved materials, including lowloss dielectric materials to avoid unwanted loss on the metasurface, and materials that can withstand moderately high temperatures, with optical properties robust against temperature variations. Considering these issues, SiO_{2} and Si are good candidates for these applications. Both materials have high melting points and their permittivity is stable with temperature change [43,44]. Also, the permittivity gap between SiO_{2} and Si is relatively high, which provides good contrast to build dielectric metasurfaces [45]. For the absorptive layer, we consider CopperIndiumGalliumSelenide (CIGSe). CIGSe is an ntype photovoltaic material that provides higher efficiency in light absorption compared to other ntype materials like ZnO or CdS [46,47].
Fig. 1 (a) Schematic of the geometry under consideration. Light is shined from the normal direction with electric field E_{z} and an admittance surface Y_{z}(x) over a thin substrate and a ground plane. (b) Sketch of the relation between incident power P_{inc} and deflected power P_{out}. When the metasurface is lossless, power is conserved in the system. (c) Geometry of interest to maximize deflection, assuming a lossless superstrate, i.e., ignoring the imaginary part of permittivity for the absorbing material. Scattered electric field profile for oneway and twoway deflection. For twoway deflection, the reflection phase is π/2 for both beams. Frequency and deflection angle are set to 300 THz and 60°,respectively (d) Admittance profile for oneway and twoway deflection, used in panel (c), and calculated reflection efficiency for both cases. 
2 Theoretical analysis
The purpose of this work is to show how metasurfaces can be effective in increasing the absorption efficiency in thin layers. The geometry is shown in Figure 1a, and it corresponds to an ideal metasurface, backed by a substrate of thickness d_{subs}, assumed to be subwavelength, and a ground plane. When the wavelength in the absorptive material is λ and the incidence and deflection angles of the metasurface are θ_{i} = 0^{∘} and θ_{r}, respectively, the metasurface periodicity L is given by L = λ/sinθ_{r} at the frequency of interest. Once the periodicity is set for a specific deflection angle, the corresponding metasurface supports propagation channels in a discrete number of diffraction orders. For the calculation of admittances and deflection efficiency, we assume that the absorptive layer is lossless, discarding the imaginary part of the index. We also consider the case of surface admittance to be a scalar Y_{z}(x), which corresponds to the case of isotropic surfaces, or of absence of polarization coupling under an incident electric field and impinging from the y direction. The desired wave number of the deflected beam is therefore , where is the propagation constant in the superstrate layer, and ± signs refer to the direction of the deflected beams in the transverse plane. The required admittance to deflect light towards one of the two anomalous reflection channels can be derived based on the analysis in [41,42]. With incident angle θ_{i} = 0^{∘}, the admittance profile is (1)
If instead we want to deflect light towards two anomalous reflection channels with reflection coefficients Γ_{t1}, Γ_{t2}, the required admittance profile becomes (2)
The imaginary part in both expressions compensates the phase delay introduced by the substrate. k_{subs} is the wave number in the substrate and ϵ_{subs} is the corresponding permittivity. Power conservation imposes some constraints on the amplitude of the reflection coefficients to ensure a globally lossless metasurface, as sketched in Figure 1b. In particular, for a metasurface that does not globally provide energy to the impinging wave, the tilt to an oblique angle from normal incidence implies that there is an increase in power density, proportional to 1/cosθ_{r} for a single deflection angle. As noticed in [41], even for a globally lossless metasurface, equation (1) implies the need of a continuous combination of loss and gain across the surface to ensure unitary efficiency, and this need can be mitigated with the use of more advanced metasurface designs [39]. The admittance profile for deflection towards two channels, as in equation (2), has similar challenges.
Figure 1c shows the scattered Efield when the admittance is designed to deflect the incident impinging energy towards 60° propagating into one and two directions, respectively for the simulation panel on the left and on the right. The field profile for oneway deflection clearly shows that the beam is deflected towards 60°, and two ways deflection shows the interference of waves propagating in opposite directions. Energy conservation is achieved by choosing the proper amplitude of Γ, but the need for active/passive impedance distributions to ensure 100% efficiency in deflection is hard to realize in various applications. For this reason, in the following we design the surfaces using only the imaginary part of the required admittance profile, and discarding the real part, as suggested in [41]. This approximation is accurate as long as the deflection angle is not extreme.
The phase relationship between the two reflected beams in twoway deflection mode can be adjusted at will from 0 to 2π. When both reflection coefficients have the same phase of π/2, as considered in Figure 1c, right panel, the required impedance profile ensures minimized real part, therefore enabling the strongest coupling efficiency using a fully passive metasurface. For this reason, in the following, we choose this specific configuration for the twodeflection metasurface. The top panel in Figure 1d shows the values of and extracted from equation (1) and (2) for θ_{r} = 60^{∘}at 300 THz. In the bottom panel, we plot the calculated reflection coefficient towards the anomalous direction in the two cases of oneway and twoway deflection over a broad range of frequencies, beyond the design frequency. Due to the finite substrate thickness, the reflection efficiency drops slowly when frequency is increased, with the residual power being channeled towards normal incidence. This panel clearly shows the broadband nature of the gradient metasurface approach, which is a significant advantage for solar energy [34,42].
We now add the loss in the superstrate layer, and explore ways to use the wave deflection to enable broadband absorption. Figure 2a shows the absorption efficiency for the admittance profiles in Figure 1d. The red solid line corresponds to twoway deflection and the blue solid line to oneway deflection. Both and achieve high absorption compared to the case with no metasurface, over a broad range of angles. In the plot, we compare the absorption to the case in which the absorptive substrate is backed by a perfect electric conductor (PEC) and by a perfect magnetic conductor (PMC), and average the two. The reason for this specific choice is that the boundary condition in equation (1) and (2) imposes a phase of the reflection coefficient in the transverse direction that spans from 0 to ∞, i.e., it gradually varies from the phase of a PMC and a PEC boundary, as sketched in Figure 2b.
For realistic metasurfaces, we need to consider the discretization of the ideal admittance profile. In addition, field coupling between the various subsections plays an important role. This problem can be handled by adjusting the difference in permittivity between the considered materials [31]. The index of the superstrate also affects the efficiency of metasurfaces. With a high index layer, the phase varies over a short distance, complicating the design. In this work, Si and SiO_{2} are used to realize the metasurface, and CIGSe is the absorbing superstrate. The permittivity of CIGSe is around 8 and permittivity of Si and SiO_{2} is approximately 12 and 2, respectively, which is a sufficient contrast to realize efficient twoway deflection, but it does not provide good performance for the case of oneway deflection, as discussed in the following section.
Fig. 2 (a) Absorption efficiency when ideal metasurfaces are used beneath the substrate compared to the case of simple reflector backing. (b) Relationship between PEC and PMC boundary conditions and admittance. (c) Schematic of the realistic geometry for our simulations, d_{cigse} is 100 nm and d_{subs} is 50 nm. Periodicity L and jIm[Y_{z}(x)] are changed for each deflection angle and frequency. 
3 Results
3.1 Ideal metasurfaces
We start considering the case of ideal metasurface profiles j Im [Y_{z}(x)] applied on top of a SiO_{2} substrate. We consider deflection angles from 0° to 90° in steps of 5°, and a frequency range from 280 THz to 600 THz for the operation frequency. The sketch of the geometry in our simulation is shown in Figure 2c. The thickness of the absorbing CIGSe superstrate is 100 nm. We show in Figure 3a and b the total absorption for oneway, and twoway metasurfaces. For twoway metasurfaces, phases of both beams are set to 0.5π making the relative phase of 0 and the sum of π, which maximizes the effect of imaginary part as mentioned above. Absorption efficiency tends to increase with frequency, as expected, because of the increased electrical thickness of the CIGSe layer. Absorption increases with the deflected angle, and an absorption peak is observed around 60° to 70°. Critical angle at the CIGSe to air interface is around 70° in the entire frequency range considered here, so that the total reflection contributes to increase light trapping, and boosts the absorption efficiency to close to 100% over a broad bandwidth and angular range. Given that the decay constant in CIGSe at 400 THz is α = −20.3 × 10^{6}/m, we calculate that 35% of energy is absorbed over one pass in 100 nm thickness. Overall area of 2D color map shows high absorption, but there are several points where absorption is low, especially in the left side of the plots, for which the electrical length of the superstrate is shorter, and therefore the optimal choice of deflection angle is more important.
The absorption efficiency in Figure 3a and b is calculated assuming that the admittance profiles are designed optimally for each deflection angle and frequency. In practice, once a metasurface is designed and realized, the periodicity is fixed by the design frequency and angle, and there is a natural dispersion of anomalous reflection at different frequencies. We consider this effect by plotting black dashed lines in Figure 3a and b, which show the dispersion of deflection angle with frequency, and may be considered realistic regions over which broadband absorption can be achieved with a fixed metasurface period.
Figure 3c, d show the same data following the dashed lines. In this case, the deflection angle in the vertical axis is defined based on designs at 300 THz. In these plots, we can see more clearly the optimal choice of metasurface periodicity to enable broadband absorption. High absorption can be clearly achieved at specific periodicity values.
Fig. 3 (a) and (b) show the absorption efficiency for jIm[Y_{z}(x)] beneath a thin CIGSe layer. The black dashed lines consider the natural angular dispersion with frequency for a fixed period, and the labels correspond to 400 THz, with deflection angles from 10° to 80°. (c) and (d) show the same results for metasurfaces wtih fixed periodicity. 
3.2 Realistic metasurfaces
Several approaches have been studied to implement realistic metasurfaces that can tailor the impinging beams at will. In this study, phasegradient metasurfaces are considered, due to their inherent broad bandwidth and design robustness. Since the deflection angle required for light trapping is around 60°–70°, based on the results in the previous section, the deflection efficiency even in the case of totally passive gradient metasurfaces is expected to be rather high. After some optimizations, we have found that discretization with three unitcells per period is a reasonable tradeoff between fabrication complexity and absorption efficiency. Figure 4a shows the designed metasurfaces for both oneway and twoway deflections (top and bottom, respectively), using Si and SiO_{2} metasurfaces. By sweeping the width of Si blocks in SiO_{2}, we can derive the relative phase of the local reflection coefficient, which synthesizes the required discretized admittance profile. In these results, we assumed again d_{meta} = 100 nm and d_{sub} = 50 nm at 400 THz. From this plot, it is clear that, for the given materials, it is not possible to realize a complete 360° phase span, which makes it particularly challenging to realize oneway deflection metasurfaces. However, metasurfaces for twoway deflection can be fabricated since due to symmetry, they can be realized using a single Si block per period.
Figure 4b shows the calculated absorption for optimized realistic metasurfaces over the CIGSe layer. After discretization, we have found some small deviations on the optimal deflection angles compared to the ideal metasurface scenario, and we show here the case of 30° and 60°, which correspond to optimal choices for twoway discretized deflection metasurfaces, as seen in Figure 3d. The simulations confirm that it is possible to achieve good broadband absorption with a peak efficiency over 95%, and a significant improvement compared to the case with no metasurfaces. Field profiles for each deflection angle at the design frequency of 400 THz are shown in the insets of Figure 4b, confirming the deflection efficiency and large light trapping. These symmetric metasurfaces for twoway deflection may appear consistent with other approaches for nanophotonic management of solar cells, using Mie resonant structures [47–50]. However, here we consider nonresonant blocks, geared at manipulating the local phase of the reflection coefficient for broadband light trapping, and purposefully avoiding single resonant elements associated to narrower bandwidths of operation.
Fig. 4 (a) Phase profile when nanoparticle width is sweeped inside one periodicity for a threeblock discretized metasurface. Si and SiO_{2} are used for making the metasurface. Sketch in the right shows the geometry of the discretized metasurfaces. (b) When the frequency is set at 400 THz, absorption has a similar value as in the case of ideal metasurfaces. Both cases are better than in the case with no metasurface. The right panel shows the scattered Efield profiles, confirming large light trapping. 
4 Conclusions
Metasurfaces can offer interesting opportunities for enhanced absorption in thin layer materials. These may be of interest for thinfilm solar cell applications, as well as for light emission enhancement in LEDs. In this paper, we first derived the optimal performance for light deflection and trapping assuming ideal admittance profiles, and then we applied these results to realistic dielectric metasurfaces. Our results show that high value of absorption efficiency may be achieved considering both oneway and twoway deflection metasurfaces, but given the constraints on fabrication in the visible range, twoway metasurfaces may provide an easier path to the practical implementation of these structures. We believe that these broadband nanophotonic solutions to absorption enhancement may have an impact in various applications of current interest, including photovoltaics and light emission.
Acknowledgments
This work was supported in part by the Air Force Office of Scientific Research and the Welch Foundation with grant No. F1802. We acknowledge useful discussions with V. Neder and A. Polman.
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Cite this article as: Hoyeong Kwon, Hamidreza Chalabi, Andrea Alù, Broadband absorption with gradient metasurfaces, EPJ Appl. Metamat. 2018, 5, 4
All Figures
Fig. 1 (a) Schematic of the geometry under consideration. Light is shined from the normal direction with electric field E_{z} and an admittance surface Y_{z}(x) over a thin substrate and a ground plane. (b) Sketch of the relation between incident power P_{inc} and deflected power P_{out}. When the metasurface is lossless, power is conserved in the system. (c) Geometry of interest to maximize deflection, assuming a lossless superstrate, i.e., ignoring the imaginary part of permittivity for the absorbing material. Scattered electric field profile for oneway and twoway deflection. For twoway deflection, the reflection phase is π/2 for both beams. Frequency and deflection angle are set to 300 THz and 60°,respectively (d) Admittance profile for oneway and twoway deflection, used in panel (c), and calculated reflection efficiency for both cases. 

In the text 
Fig. 2 (a) Absorption efficiency when ideal metasurfaces are used beneath the substrate compared to the case of simple reflector backing. (b) Relationship between PEC and PMC boundary conditions and admittance. (c) Schematic of the realistic geometry for our simulations, d_{cigse} is 100 nm and d_{subs} is 50 nm. Periodicity L and jIm[Y_{z}(x)] are changed for each deflection angle and frequency. 

In the text 
Fig. 3 (a) and (b) show the absorption efficiency for jIm[Y_{z}(x)] beneath a thin CIGSe layer. The black dashed lines consider the natural angular dispersion with frequency for a fixed period, and the labels correspond to 400 THz, with deflection angles from 10° to 80°. (c) and (d) show the same results for metasurfaces wtih fixed periodicity. 

In the text 
Fig. 4 (a) Phase profile when nanoparticle width is sweeped inside one periodicity for a threeblock discretized metasurface. Si and SiO_{2} are used for making the metasurface. Sketch in the right shows the geometry of the discretized metasurfaces. (b) When the frequency is set at 400 THz, absorption has a similar value as in the case of ideal metasurfaces. Both cases are better than in the case with no metasurface. The right panel shows the scattered Efield profiles, confirming large light trapping. 

In the text 
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